This is the facial expression they chose, from about twelve options, some of which had big smiles. They felt that this photo was really her. She is a serious person by nature and was not a very relaxed model.
I find that the calm gentle smile I like to go for is often the toughest expression to coax out of models. Either they grin in response to something we're talking about during the photo shoot, or they are quite serious.
To answer your other question, she doesn't have braces.
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