One of the things you'll want to do is customize your standard toolbar. Go to View | Toolbars. Highlight Standard Toolbar and click Customize. In the screen shot below, I've shown the icon for the Browser which is one of the first things you'll want to add. Other things will take time to understand and you can add them to the Standard Toolbar after gaining more familiarity.
I just installed Photoshop 7 myself and this is my first upgrade since Photoshop 4. I've used it a few times and it appears to be much improved. Photoshop has taken time to add in web features that PSP had long ago. For example, all web colors need to be expressed in hexadecimal format. PSP had the ability to convert RGB to hex long before Photoshop. 7.0 does have this ability. But, one of my PSP favorites is still not in Photoshop: mouse over any image and the height and width in pixels shows in the status bar.
|